Vol 5 Issue 1 March 2018-August 2018
S.O. EGBUNA, C.S. ANINWEDE
Abstract:Studies were carried out on the production of alkyd resin from castor and soybean seed oils respectively. Castor and soybean oils extracted from their respective seeds were refined to remove any unwanted materials and then characterized to determine their physicochemical properties such as acid value, iodine value, saponification value, etc. The results showed that the relatively high iodine content of soybean makes it naturally a suitable vegetable oil for the synthesis of quality alkyds, while the low iodine content of castor oil indicated that it is a non-drying oil and therefore not suitable for the production of quality alkyds. In this present study, castor oil was severely dehydrated to increase its degree of unsaturation as indicated by its high iodine content after dehydration; thus making it suitable for the synthesis of quality alkyds. Monoglyceride method was used in the synthesis of medium oil alkyd resins of 50% oil length from appropriate amount of glycerol and each oil via alcoholysis, followed by addition of phthalic anhydride by esterification. The produced resins were characterized using standard methods, tested for their coating properties such as drying time, chemical resistance, solubility in different solvents, etc. The resins were equally analyzed using Fourier Transform Infrared Spectroscopy (FTIR) to determine their structural functionalities. The results obtained showed that both soybean and dehydrated castor oil modified resins have desirable qualities, though soybean oil modified resin has preferred coating properties.
Keywords:Alkyd Resin, Soybean Oil, Castor Oil, Monoglyceride Method, Esterification.
Title:COMPARATIVE ANALYSIS OF ALKYD RESINS PRODUCED FROM CASTOR AND SOYBEAN SEED OILS
Author:S.O. EGBUNA, C.S. ANINWEDE
ISSN 2394-7349
International Journal of Novel Research in Engineering and Science
Novelty Journals